I used replace color again to give more saturation on the shadow part. The light bounce from skin will get a little red and orange because subsurface scattering.
And I used Selective Color again to give the high light part a little blue, because many tiny vein under the skin.
I used basic paint brush to paint the lips and eyes make up.
and then, use Hue/Saturation tool to get the basic color of chair sofa.
Use replace color to give the dark side more red, looks like purple.